The U.S. Geological Survey (USGS) has developed the National Land Cover Database (NLCD) to provide consistent land cover and land cover change products for the nation since 2001. As one of products in the NLCD, the percent impervious surface area (ISA), which was estimated with Landsat imagery, represents the fraction of human-made impervious area in a 30-m grid and has been used to quantify urban land cover types and extents for the United States. However, it is still a challenge to clearly determine urban land cover intensity and extents using remote sensing data with spatial and spectral resolutions similar to Landsat in part because of highly heterogeneous features of urban land cover. Most urban areas, especially in low intensity development areas, exhibit sub-pixel characteristics that mix impervious surface with other land covers (e.g., grass and trees) in the 30-m resolution satellite imagery. Furthermore, the influence of highly heterogeneous features in many urban areas and how they alter the spectral signature of urban landscapes has not yet been fully studied. Recent advances in remote sensing technology have provided multiple spectral and spatial resolution data from several satellites including WorldView (WV), Sentinel-2, and the Landsat Operational Land Imager (OLI). Remote sensing images having different spectral bands and high spatial resolution provide the potential to derive detailed information on the nature and properties of different surface materials on the urban ground. This study focuses on performance of mapping impervious surface using data collected from WorldView-3, Sentinel-2, and Landsat OLI. We compared ISA results estimated from these sensors and evaluated benefits and limitations of radiometric and spatial resolutions for mapping impervious surface in a study area on the Eastern corridor between Washington, D.C., and Baltimore, where developed impervious surface containing both residential housings, office buildings, and roads, in the United States. The impact of different band combinations in Sentinel-2 imagery on mapping urban impervious surface and urban land cover was also evaluated.