Kovats and lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest
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Abstract
Retention indices of standard organic compounds of environmental interest were determined by gas chromatography/mass spectrometry, using a DB‐5 fused‐silica capillary column. Retention indices are useful references for tentative compound identification by gas chromatography, or confirmation by gas chromatography/mass spectrometry. They provide elution order for isomers that might be indistinguishable based on mass spectra. Modified Kovats and Lee retention indices are given for polycyclic aromatic hydrocarbons; sulfur heterocycles; nitrogen heterocycles; aromatic amines; oxygen heterocycles; phenols; alcohols; ketones; alkanes; nitriles; and methylesters of fatty, dicarboxylic, and aromatic acids for comparison and reference. Retention index values for heterocycles by gas chromatography/mass spectrometry are comparable with gas chromatography values previously reported.
Publication type | Article |
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Publication Subtype | Journal Article |
Title | Kovats and lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest |
Series title | Journal of Separation Science |
DOI | 10.1002/jhrc.1240090603 |
Volume | 9 |
Issue | 6 |
Year Published | 1986 |
Language | English |
Publisher | Wiley |
Description | 7 p. |
First page | 328 |
Last page | 334 |
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