Three geochemical methods were used to determine chemical reactions that control solute concentrations in the Snake River Plain regional aquifer system: (1) Calculation of a regional solute balance within the aquifer and of mineralogy in the aquifer framework to identify solute reactions, (2) comparison of thermodynamic mineral saturation indices with plausible solute reactions, and (3) comparison of stable-isotope ratios of the ground water with those in the aquifer framework. The geothermal ground-water system underlying the main aquifer system was examined by calculating thermodynamic mineral saturation indices, stable-isotope ratios of geothermal water, geothermometry, and radiocarbon dating.

Water budgets, hydrologic arguments, and isotopic analyses for the eastern Snake River Plain aquifer system demonstrate that most, if not all, water is of local meteoric and not juvenile or formation origin. Solute-balance, isotopic, mineralogic, and thermodynamic arguments suggest that about 20 percent of the solutes are derived from reactions with rocks forming the aquifer framework.

Solute reactions indicate that calcite and silica are precipitated in the aquifer. Mineralogic evidence and thermodynamic arguments suggest that olivine, pyroxene, pyrite, and anhydrite are being dissolved and plagioclase is being weathered. Large amounts of sodium and chloride, relative to their concentration in the igneous rock, are being removed from the aquifer. Release of fluids from inclusions in the igneous rocks, and initial flushing of grain boundaries and pores of detrital marine sediments in interbeds are believed to be the source of the sodium chloride. Identification and quantification of reactions controlling solute concentrations in ground water in the eastern plain indicate that the aquifer is not a large mixing vessel that simply stores and transmits water and solutes but is undergoing diagenesis and is both a source and sink for solutes.

Evaluation of solute concentrations and stable-isotope ratios of hydrogen, oxygen, carbon, and sulfur along ground-water flowpaths that transect irrigated areas suggests that irrigation water may have altered solute concentrations and isotope ratios in the eastern Snake River Plain aquifer system. The changes, however, have been small, owing to similarity of solute concentrations in applied irrigation water and in native ground water and rapid movement and large dispersivity of the aquifer.

Reactions controlling solutes in the western Snake River basin are believed to be similar to those in the eastern basin but, because of different hydrologic conditions, a definitive analysis could not be made.

The regional geothermal system that underlies the Snake River Plain contains total dissolved solids similar to those in the overlying Snake River Plain aquifer system but contains higher concentrations of sodium, bicarbonate, silica, fluoride, sulfate, chloride, arsenic, boron, and lithium, and lower concentrations of calcium, magnesium, and hydrogen. These solutes are believed to be derived from reactions similar to those in the Snake River Plain aquifer system, except that ion exchange may be a significant mechanism controlling solute concentrations in the geothermal system.

Geothermometry calculations of selected ground-water samples from known geothermal areas throughout the basin suggest that the geothermal system is large in areal extent but has relatively low temperatures. Approximately half of the silica-quartz calculated water temperatures are greater than 90 degrees Celsius. Radiocarbon dating of geothermal water in the Salmon Falls and Bruneau-Grand View areas in the south-central part of the Snake River basin suggests that residence time of the geothermal water is about 17,700 years.