Linear solvation energy relationships (LSER): 'rules of thumb' for Vi/100, π*, Βm, and αm estimation and use in aquatic toxicology

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Abstract

This chapter provides a listing of the increasing variety of organic moieties and heteroatom group for which Linear Solvation Energy Relationship (LSER) values are available, and the LSER variable estimation rules. The listings include values for typical nitrogen-, sulfur- and phosphorus-containing moieties, and general organosilicon and organotin groups. The contributions by an ion pair situation to the LSER values are also offered in Table 1, allowing estimation of parameters for salts and zwitterions. The guidelines permit quick estimation of values for the four primary LSER variables Vi/100, π*, Βm, and αm by summing the contribtuions from its components. The use of guidelines and Table 1 significantly simplifies computation of values for the LSER variables for most possible organic comppounds in the environment, including the larger compounds of environmental and biological interest.

Additional publication details

Publication type Book chapter
Publication Subtype Book Chapter
Title Linear solvation energy relationships (LSER): 'rules of thumb' for Vi/100, π*, Βm, and αm estimation and use in aquatic toxicology
Chapter 23
Year Published 1996
Language English
Publisher CRC Press
Contributing office(s) Great Lakes Science Center
Description 23 p.
Larger Work Type Book
Larger Work Subtype Monograph
Larger Work Title Techniques in aquatic toxicology
First page 435
Last page 457
Online Only (Y/N) N
Additional Online Files (Y/N) N