Can arsenic occurrence rate in bedrock aquifers be predicted?

Environmental Science & Technology
By: , and 

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Abstract

A high percentage (31%) of groundwater samples from bedrock aquifers in the greater Augusta area, Maine was found to contain greater than 10 μg L–1 of arsenic. Elevated arsenic concentrations are associated with bedrock geology, and more frequently observed in samples with high pH, low dissolved oxygen, and low nitrate. These associations were quantitatively compared by statistical analysis. Stepwise logistic regression models using bedrock geology and/or water chemistry parameters are developed and tested with external data sets to explore the feasibility of predicting groundwater arsenic occurrence rates (the percentages of arsenic concentrations higher than 10 μg L–1) in bedrock aquifers. Despite the under-prediction of high arsenic occurrence rates, models including groundwater geochemistry parameters predict arsenic occurrence rates better than those with bedrock geology only. Such simple models with very few parameters can be applied to obtain a preliminary arsenic risk assessment in bedrock aquifers at local to intermediate scales at other localities with similar geology.

Publication type Article
Publication Subtype Journal Article
Title Can arsenic occurrence rate in bedrock aquifers be predicted?
Series title Environmental Science & Technology
DOI 10.1021/es203793x
Volume 46
Issue 4
Year Published 2012
Language English
Publisher American Chemical Society
Contributing office(s) Maine Water Science Center
Description 8 p.
First page 2080
Last page 2087
Online Only (Y/N) N
Additional Online Files (Y/N) N
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